Bis{benzyl 2-[4-(4-methoxyphenyl)butan-2-ylidene]hydrazinecarbodithioato-κ2 N 2,S}nickel(II)
نویسندگان
چکیده
The complete mol-ecule of the title complex, [Ni(C(19)H(21)N(2)OS(2))(2)], is generated by the application of twofold symmetry. The Ni(II) atom is N,S-chelated by two hydrazinecarbodithio-ate ligands, which provide an N(2)S(2) donor set that defines a distorted square-planar geometry, the S atoms being approximately cis. The conformation of the chelate ring is an envelope with the Ni(II) atom being the flap atom. The dihedral angle between the least-squares planes through the chelate rings = 30.10 (6)°. Supra-molecular chains propagated by glide symmetry along the c axis and mediated by C-H⋯N contacts feature in the crystal packing.
منابع مشابه
Bis{2-[3-(hydroxyimino-κN)butan-2-ylidene]-N-methylhydrazinecarbothioamide-κ2 N 2,S}nickel(II) dichloride
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متن کاملBis[benzyl N′-(3-phenylprop-2-enylidene)hydrazinecarbodithioato-κ2 N′,S]zinc(II)
In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis. The crystal structure is further stabilized by C-...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012